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The Baker–Venkataraman rearrangement is the chemical reaction of 2-acetoxyacetophenones with base to form 1,3-diketones.
This rearrangement reaction proceeds via enolate formation followed by acyl transfer. It is named after the scientists Wilson Baker and K. Venkataraman.
The Baker–Venkataraman rearrangement is often used in the synthesis of chromones and flavones. After the base-catalyzed rearrangement, treatment with acid generally affords the chromone or flavone core, though other milder methods have been reported.